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KMID : 1024520140230091609
Journal of the Environmental Sciences
2014 Volume.23 No. 9 p.1609 ~ p.1618
Adsorption Characteristics of Cobalt, Strontium, and Cesium on Natural Soil and Kaolin
Cheon Kyeong-Ho

Choi Jeong-Hak
Shin Won-Sik
Choi Sang-June
Abstract
In this study, as a fundamental study for the remediation of the radionuclides-contaminated soil, the adsorption of cobalt, strontium, and cesium on natural soil and kaolin were experimently investigated and adsorption characteristics were evaluated by using several adsorption kinetic and isotherm models. The pseudo-first-order kinetic model (PFOM), pseudo-second-order kinetic model (PSOM), one-site mass transfer model (OSMTM), and two compartment first-order kinetic model (TCFOKM) were used to evaluate the kinetic data and the pseudo-second-order kinetic model was the best with good correlation. The adsorption equilibria of cobalt, strontium, and cesium on natural soil were fitted successfully by Redlich-Peterson and Sips models. For kaolin, the adsorption equilibria of cobalt, strontium, and cesium were fitted well by Redlich-Peterson, Freundlich, and Sips models, respectively. The amount of adsorbed radionuclides on natural soil and kaolin was in the order of cesium > strontium > cobalt. It is considered that these results could be useful to predicting the adsorption behaviors of radionuclides such as cobalt, strontium, and cesium in soil environments.
KEYWORD
Adsorption, Radionuclides, Cobalt, Strontium, Cesium, Natural soil, Kaolin
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